Ampcera™ LLZO Nano Powder, Nb-doped, Li_6.5La₃Zr_1.5Nb_0.5O₁₂, Niobium Doped Lithium Lanthanum Zirconate Garnet Powder, Solid State Electrolyte for Advanced Lithium Batteries, 100g, 500nm D50

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Product Number: PO0104
Vendor: Ampcera Inc.
Composition: Li_6.5La₃Zr_1.5Nb_0.5O₁₂ (Nb-doped LLZO, LLZNO), Niobium doped Lithium Lanthanum Zirconate Garnet
Theoretical Density: 5.2 g/cm³
Particle Size: D50 = ~500 nm, D10 ~ 300nm, D90 ~ 800nm
Purity: 99.9%
Calcination temperature: <1000°C
Bulk Ionic Conductivity: >5 x 10^-4 S/cm at room temperature
Product Form: Nano Powder

Applications: Solid state electrolyte material for all solid state lithium ion batteries. Niobium doped LLZO, with nominal composition Li_6.5La₃Zr_1.5Nb_0.5O₁₂ (Nb-doped LLZO), is used as a solid electrolyte material for Li-based solid state battery because of its high Lithium ionic conductivity and chemical stability with respect to lithium metal as well as its stability at elevated temperatures. Because of its better electrochemical stability, LLZO is preferred than LLTO as a solid electrolyte material.

*All solid state electrolyte materials sold by MSE Supplies are under the trademark of Ampcera.

Powder processing equipment: HIGH ENERGY VERTICAL PLANETARY BALL MILL FOR BATTERY MATERIALS PROCESSING

GLOVE BOX HIGH ENERGY VERTICAL PLANETARY BALL MILL FOR BATTERY MATERIALS PROCESSING

References

Jeffrey W. Fergus, Ceramic and polymeric solid electrolytes for lithium-ion batteries, Journal of Power Sources, Volume 195, Issue 15, 1 August 2010, Pages 45544569; http://dx.doi.org/10.1016/j.jpowsour.2010.01.076
Zhi Deng, Yifei Mo and Shyue Ping Ong, Computational studies of solid-state alkali conduction in rechargeable alkali-ion batteries, NPG Asia Materials (2016) 8, e254; doi:10.1038/am.2016.7
Seungho Yu, Robert D. Schmidt, Regina Garcia-Mendez, Erik Herbert, Nancy J. Dudney, Jeffrey B. Wolfenstine, Jeff Sakamoto, and Donald J. Siegel, Elastic Properties of the Solid Electrolyte Li₇La₃Zr₂O₁₂ (LLZO), Chem. Mater., 2016, 28 (1), pp 197206. DOI: 10.1021/acs.chemmater.5b03854
Jiajia Tan and Ashutosh Tiwari, Synthesis of Cubic Phase Li₇La₃Zr₂O₁₂ Electrolyte for Solid-State Lithium-Ion Batteries, Electrochem. Solid-State Lett. 2012 volume 15, issue 3, A37-A39. doi: 10.1149/2.003203esl
X. Han, et. al., Negating interfacial impedance in garnet-based solid-state Li metal batteries, Nature Materials volume 16, pages 572579 (2017)

Solid electrolytes open doors to solid-state batteries