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MSE PRO CPhos Pd G<sub>3</sub>, 98.0% Purity - MSE Supplies LLC

MSE PRO CPhos Pd G3, 98.0% Purity

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MSE PRO™ CPhos Pd G3, 98.0% Purity

MSE PRO™ CPhos Pd G3 is a modified G3 precatalyst (G3') that was developed to enhance catalytic activity and selectivity. The complex is composed of [(2-Dicyclohexylphosphino-2',6'-bis(N,N-dimethylamino)-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)] palladium(II) methanesulfonate. This design combines the advantages of both phosphine and amine ligands, resulting in a highly effective catalyst for cross-coupling reactions.

MSE Supplies offers various catalysts and ligands for coupling reaction. Please contact us for customization or bulk orders.

Technical Specifications:

CAS No. 1447963-73-6
Chemical name CPhos Pd G3
Synonym(s)
  • CPhos Palladacycle gen. 3
  • Methanesulfonato(2-dicyclohexylphosphino-2', 6'-bis(dimethylamino)-1, 1'-biphenyl)(2'-amino-1, 1'-biphenyl-2-yl)palladium(II)
Molecular formula C41H54N3O3PPdS
Pack size

1 g (CM1327)

5 g (CM1328)
Molecular weight 806.35 g/mol
Melting point 176-178 °C (decomposition)
Purity ≥98.0 %
Appearance White to off-white powder
Storage  2-8 °C, protect from light, stored under nitrogen


References:

[1] Lou, Y. G., Wang, A. J., Zhao, L., He, L. F., Li, X. F., He, C. Y., & Zhang, X. (2019). Palladium-catalyzed cross-coupling of unactivated alkylzinc reagents with 2-bromo-3, 3, 3-trifluoropropene and its application in the synthesis of fluorinated amino acids. Chemical communications, 55(26), 3705-3708.

[2] Reichert, E. C. (2023). Development of Deactivation-Resistant Catalysts for Pd-Catalyzed C–N Cross-Coupling Reactions (Doctoral dissertation, Massachusetts Institute of Technology).