MSE PRO [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), 98% Purity

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MSE PRO™ [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

, 98% Purity

MSE PRO™ [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (Pd(dppf)Cl₂) is a coordination complex containing a palladium(II) center bound to two chloride ligands and the chelating dppf (1,1'-bis(diphenylphosphino)ferrocene) ligand. The dppf ligand is a bidentate phosphine ligand derived from ferrocene, providing steric bulk and electron-richness to stabilize the Pd(0) and Pd(II) oxidation states. This complex is widely used as a catalyst in various organic synthesis reactions, particularly in transition metal-catalyzed cross-coupling reactions.

MSE Supplies offers various catalysts and ligands of coupling reaction. Please contact us for customization or bulk orders.

Technical Specifications:

CAS No.	72287-26-4
Chemical name	[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Synonym(s)	Pd(dppf)Cl₂ Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II)
Molecular formula	(C₁₇H₁₄P)₂Fe · PdCl₂
Pack size	5 g (CM1345); 10 g (CM1346)
Molecular weight	731.7 g/mol
Purity	98 %
Melting point	275-280 °C
Stability	Hygroscopic
Appearance	Red to very dark red powder
Storage	Keep in dark place, inert atmosphere, room temperature

Reference:

[1] Zeng, M., Du, Y., Shao, L., Qi, C., & Zhang, X. M. (2010). Palladium-catalyzed reductive homocoupling of aromatic halides and oxidation of alcohols. The Journal of Organic Chemistry, 75(8), 2556-2563.

[2] Štěpnička, P., Císařová, I., & Schulz, J. (2011). Coordination and Catalytic Properties of a Semihomologous Dppf Congener, 1-(Diphenylphosphino)-1′-[(diphenylphosphino) methyl] ferrocene. Organometallics, 30(16), 4393-4403.