Ampcera® LLZO Nano Powder, Cubic Phase Ga-doped, Li_6.4Ga_0.2La₃Zr₂O₁₂, Gallium Doped Lithium Lanthanum Zirconate Garnet, 100g, D50 is between 300 and 500nm

Product SKU Number: PO0141
Ampcera™ LLZO Nano Powder, Ga-doped, Li_6.4 Ga_0.2La₃Zr₂O₁₂, Gallium Doped Lithium Lanthanum Zirconate Garnet Powder, Solid State Electrolyte for Advanced Lithium Batteries
Composition: Li_6.4 Ga_0.2La₃Zr₂O₁₂(Ga-doped LLZO), Gallium doped Lithium Lanthanum Zirconate Garnet
Theoretical Density: ~5.3 g/cm³
Particle Size: D50 = 300 nm ~ 500 nm

typical D10 = 200 nm
typical D50 = 330 nm
typical D90 = 2100 nm (2.1 um)

Purity: synthesized from 99.9% precursor materials
Phase: cubic phase, garnet structure LLZO
Calcination temperature: <1000°C
Bulk Ionic Conductivity: >5 x 10^-4 S/cm at room temperature
Product Form: Nano Powder / Sub-micron Powder

XRD spectrum of the Ampcera Ga-doped LLZO nano powder (Product SKU# PO0141) is shown below.

Applications

Solid state electrolyte material for all solid state lithium ion batteries. Gallium doped LLZO, with nominal composition Li_6.4 Ga_0.2La₃Zr₂O₁₂(Ga-doped LLZO), is used as a solid electrolyte material for Li-based batteries because of its high Lithium ionic conductivity and chemical stability with respect to lithium as well as its stability at elevated temperatures.

* All solid state electrolyte materials sold by MSE Supplies are under the trademark of Ampcera.

Shipping and handling: This material is classified as a hazmat and requires special packaging and shipping to comply with regulatory requirements. Please contact us for specific details with shipping and handling.

Powder processing equipment

HIGH ENERGY VERTICAL PLANETARY BALL MILL FOR BATTERY MATERIALS PROCESSING

References

Jian-Fang Wu, En-Yi Chen, Yao Yu, Lin Liu, Yue Wu, Wei Kong Pang, Vanessa K. Peterson, and Xin Guo, Gallium-Doped Li7La3Zr2O12 Garnet-Type Electrolytes with High Lithium-Ion Conductivity, ACS Appl. Mater. Interfaces 2017, 9, 2, 1542–1552
Jeffrey W. Fergus, Ceramic and polymeric solid electrolytes for lithium-ion batteries, Journal of Power Sources, Volume 195, Issue 15, 1 August 2010, Pages 45544569; http://dx.doi.org/10.1016/j.jpowsour.2010.01.076
Zhi Deng, Yifei Mo and Shyue Ping Ong, Computational studies of solid-state alkali conduction in rechargeable alkali-ion batteries, NPG Asia Materials (2016) 8, e254; doi:10.1038/am.2016.7
Seungho Yu, Robert D. Schmidt, Regina Garcia-Mendez, Erik Herbert, Nancy J. Dudney, Jeffrey B. Wolfenstine, Jeff Sakamoto, and Donald J. Siegel, Elastic Properties of the Solid Electrolyte Li7La3Zr2O12 (LLZO), Chem. Mater., 2016, 28 (1), pp 197206. DOI: 10.1021/acs.chemmater.5b03854
Jiajia Tan and Ashutosh Tiwari, Synthesis of Cubic Phase Li7La3Zr2O12 Electrolyte for Solid-State Lithium-Ion Batteries, Electrochem. Solid-State Lett. 2012 volume 15, issue 3, A37-A39. doi: 10.1149/2.003203esl
Effects of Gallium Doping in Garnet-Type Li7La3Zr2O12 Solid Electrolytes
Randy Jalem, M.J.D. Rushton, William Manalastas, Jr., Masanobu Nakayama, Toshihiro Kasuga, John A. Kilner, and Robin W. Grimes
Chemistry of Materials 2015 27 (8), 2821-2831, DOI: 10.1021/cm5045122

Solid electrolytes open doors to solid-state batteries

This product has been added to the cart.

Oxide Solid Electrolyte