Ampcera® Sulfide Solid Electrolyte, Li₃PS₄ (LPS), 75Li₂S 25P₂S₅ Powder

Composition: Li₃PS₄ (LPS), 75Li₂S-25P₂S₅ (mol%) doped with LiI

Product Number: PO0132 (10 g)

Material Type: Thiophosphate Glass-Ceramic

Ionic Conductivity: ~1 x 10^-3 S/cm (1 mS/cm) at room temperature

Theoretical Density: 1.83 g/cm3

Purity: synthesized from 99.9% precursor materials

Product Form: powder

Particle Size: typically 0.5-20 microns

Applications: solid state electrolyte material for all solid state lithium ion batteries. Previous research has shown that the addition of LiI to Li3PS4 improves the tolerance of the sulfide solid electrolyte to reduction with Li metal, and enhances the cycling performance in all-solid-state lithium metal batteries.

* All solid state electrolyte materials sold by MSE Supplies are under the trademark of Ampcera.

Powder processing equipment: GLOVE BOX HIGH ENERGY VERTICAL PLANETARY BALL MILL FOR BATTERY MATERIALS PROCESSING

Shipping and handling: This material is classified as a hazmat and requires special packaging and shipping to comply with regulatory requirements. Please contact us for specific details with shipping and handling.

References

Zhi Deng, Yifei Mo and Shyue Ping Ong, Computational studies of solid-state alkali conduction in rechargeable alkali-ion batteries , NPG Asia Materials (2016) 8, e254; doi:10.1038/am.2016.7
Yuki Kato et al. High-power all-solid-state batteries using sulfide superionic conductors, Nature Energy (2016). download pdf from the above link
Motoshi Suyama, Atsutaka Kato, Atsushi Sakuda, Akitoshi Hayashi, Masahiro Tatsumisago, Lithium dissolution/deposition behavior with Li3PS4-LiI electrolyte for all-solid-state batteries operating at high temperatures, Electrochimica Acta
Volume 286, 1 October 2018, Pages 158-162
S Adams and RP Rao, Structural requirements for fast lithium ion migration in Li₁₀GeP₂S₁₂,J. Mater. Chem., 2012,22, 7687-7691,DOI: 10.1039/C2JM16688G
Yifei Mo, Shyue Ping Ong, and Gerbrand Ceder, First Principles Study of the Li₁₀GeP₂S₁₂Lithium Super Ionic Conductor Material, Chem. Mater., 2012, 24 (1), pp 15-17, DOI: 10.1021/cm203303y
Lingzi Sang, Richard. Haasch, Andrew A. Gewirth, and Ralph G. Nuzzo, Evolution at the Solid Electrolyte/Gold Electrode Interface during Lithium Deposition and Stripping, Chem. Mater., 2017, 29 (7), pp 3029 - 3037
DOI: 10.1021/acs.chemmater.7b00034 (download PDF) LGPS powder used in this study was supplied by MSE Supplies.
Zengcai Liu, Wujun Fu, E. Andrew Payzant, Xiang Yu, Zili Wu, Nancy J. Dudney, Jim Kiggans, Kunlun Hong, Adam J. Rondinone, and Chengdu Liang, Anomalous High Ionic Conductivity of Nanoporous deg«-Li3PS4,
J. Am. Chem. Soc., 2013, 135 (3), pp 975978, DOI: 10.1021/ja3110895
Xiaona Li, Jianwen Liang, Xia Li, Changhong Wang, Jing Luo, Ruying Li and Xueliang Sun, High-performance All-Solid-State Li-Se Batteries Induced by Sulfide Electrolyte, DOI:10.1039/C8EE01621F, Energy Environ. Sci., 2018 (The Ampcera Li3SP4 solid electrolyte material supplied by MSE Supplies is the solid electrolyte material used in this research.)
Improving Cell Resistance and Cycle Life with Solvate-Coated Thiophosphate Solid Electrolytes in Lithium Batteries, Maria A. Philip, Patrick T. Sullivan, Ruixian Zhang, Griffin A. Wooley, Stephanie A. Kohn, and Andrew A. Gewirth, ACS Applied Materials & Interfaces 2019 11 (2), 2014-2021, DOI: 10.1021/acsami.8b16116

Solid electrolytes open doors to solid-state batteries

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