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tert-Butylammonium Bromide (tBABr), 99.5%, 5g - MSE Supplies LLC

High Purity tert-Butylammonium Bromide (tBABr, C4H12BrN), 99.5%, 5g

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tert-Butylammonium Bromide (tBABr, C4H12BrN), 99.5%, 5g

tert-Butylammonium Bromide (tBABr) is used as an additive for perovskite since it can provide the tert-butyl bulky group, which can promote material solubility and device stability by tuning the morphology of the perovskite films. Since the tert-butyl bulky group has larger radius, it can server as splitter, changing the perovskite crystal to 2D plates and thus changes the morphology. It is usually used for bromide-based perovskite to avoid introducing other halide ions or intentionally to introduce bromide for non-bromide-based perovskite. nBABr, iBABr and tBABr can all serve the purpose, but tBABr is the best at increasing the stability but sacrificing the most efficiency while nBABr sacrifices the least efficiency and is the worst at increasing stability (still can increase more than 20% life time though).  

Technical Data:

Product Name tert-Butylammonium Bromide
Synonym
  • tBABr
  • t-BuNH3Br
  • t-Butanamine hydrobromide
  • 2-Methyl-2-propanamine hydrobromide
  • 2-Methylpropan-2-amine hydrobromide
  • 2-Methylpropan-2-aminium bromide
SKU#
CM7019
CAS Number 60469-70-7
Chemical Formula C4H12BrN
Molecular Weight  154.05 g/mol
Appearance White Powder
Solubility Soluble in DMF, DMSO, EtOH et al.
Packaging 5 g, or as required in glass bottle
Store 25 ℃ under N2 atmosphere
Notes 1HNMR & user instruction for enquiring

References:

[1]: Origin of efficiency and stability enhancement in high‐performing mixed dimensional 2D‐3D perovskite solar cells: a review. Advanced Functional Materials 32, no. 3 (2022): 2009164.

[2]: Improving the Environmental Stability of Methylammonium-Based Perovskite Solar Cells. PhD diss., Massachusetts Institute of Technology, 2021.