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MSE PRO P(t-Bu)<sub>3</sub> Pd G4, ≥98.0% Purity - MSE Supplies LLC

MSE PRO P(t-Bu)3 Pd G4, ≥98.0% Purity

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MSE PRO™ P(t-Bu)3 Pd G4, ≥98.0% Purity

MSE PRO™ P(t-Bu)3Pd G4 is a powerful organometallic catalyst used in classic cross-coupling reactions. It consists of a palladium center coordinated to a bulky tri-tert-butylphosphine ligand and a Buchwald Fourth Generation Palladacycle. The bulky tri-tert-butylphosphine ligand and the Buchwald palladacycle scaffold provide unique reactivity and selectivity in cross-coupling reactions. This catalyst is particularly useful for the formation of C-C, C-N, and C-O bonds, enabling the synthesis of complex organic molecules.

MSE Supplies offers various catalysts and ligands of coupling reaction. Please contact us for customization or bulk orders.

Technical Specifications:

CAS No. 1621274-11-0 
Chemical name P(t-Bu)3Pd G4
Synonym(s)
  • [P(t-Bu)3 Palladacycle Gen. 4]

  • Methanesulfonato(tri-t-butylphosphino)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
Molecular formula C26H42NO3PPdS   
Pack size 5 g (CM1374)
Molecular weight
586.08 g/mol
Purity 98.1 %
Appearance Yellow powder
Storage
2-8°C, protect from light, stored under nitrogen

Reference:

[1] Reeves, E. K., Bauman, O. R., Mitchem, G. B., & Neufeldt, S. R. (2020). Solvent Effects on the Selectivity of Palladium‐Catalyzed Suzuki‐Miyaura Couplings. Israel journal of chemistry60(3-4), 406-409.

[2] Shao, L. D., Chen, Y., Wang, M., Xiao, N., Zhang, Z. J., Li, D., & Li, R. T. (2022). Palladium-catalyzed direct γ-C (sp 3)–H arylation of β-alkoxy cyclohexenones: reaction scope and mechanistic insights. Organic Chemistry Frontiers9(9), 2308-2315.