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MSE PRO Bis(triphenylphosphine)palladium(II) chloride, 98% Purity - MSE Supplies LLC

MSE PRO Bis(triphenylphosphine)palladium(II) chloride, 98% Purity

  • $ 36995
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MSE PRO™ Bis(triphenylphosphine)palladium(II) chloride, 98% Purity

MSE PRO™ Bis(triphenylphosphine)palladium(II) chloride (PdCl2(PPh3)2) is a square planar complex with two chloride ligands and two triphenylphosphine (PPh3) ligands coordinated to the central palladium(II) ion. It is an air-stable, crystalline solid that is soluble in common organic solvents like dichloromethane, chloroform. Additionally, the compound finds extensive use as a catalyst precursor in various cross-coupling reactions due to the lability of the phosphine ligands, which can be readily displaced by other ligands or substrates. Some key applications include Suzuki Coupling, Stille Coupling, Heck Reaction and Buchwald-Hartwig Amination.

MSE Supplies offers various catalysts and ligands of coupling reaction. Please contact us for customization or bulk orders.

Technical Specifications:

CAS No. 13965-03-2
Chemical name [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Synonym(s)
  • PdCl2(PPh3)2
  • Bis(triphenylphosphine)dichloropalladium(II)
Molecular formula [(C6H5)3P]2PdCl2  
Pack size

10 g (CM1347)

25 g (CM1348)
Molecular weight
701.9 g/mol
Purity 98 %
Solubility  Chloroform (slightly), dichloromethane (slightly), methanol (slightly)
Appearance Yellow powder
Storage Keep in room temperature

Reference:

[1] El Ali, B., & Fettouhi, M. (2002). PdCl2 (PPh3) 2–heteropolyacids-catalyzed regioselective hydrocarboxylation of styrene. Journal of Molecular Catalysis A: Chemical, 182, 195-207.

[2] Gelman, D., Höhne, G., Schumann, H., & Blum, J. (2001). Comparison between PdCl2 (PPh3) 2-and NiCl2 (PPh3) 2-Catalyzed Crosscoupling of Aryl Halides by Intramolecularly Stabilized Dialkylaluminum Reagents. Synthesis, 2001(04), 0591-0594.