High Purity iso-Butylammonium Bromide (iBABr, C4H12BrN), 99.5%, 3g

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SKU: CM7021
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High Purity iso-Butylammonium Bromide (iBABr, C4H12BrN), 99.5%, 3g

iso-Butylammonium Bromide (iBABr) is used as an additive for perovskite since it can provide the tert-butyl bulky group, which can promote material solubility and device stability by tuning the morphology of the perovskite films. Since the tert-butyl bulky group has larger radius, it can server as splitter, changing the perovskite crystal to 2D plates and thus changes the morphology. It is usually used for bromide-based perovskite to avoid introducing other halide ions or intentionally to introduce bromide for non-bromide-based perovskite. nBABr, iBABr and tBABr can all serve the purpose, but tBABr is the best at increasing the stability but sacrificing the most efficiency while nBABr sacrifices the least efficiency and is the worst at increasing stability (still can increase more than 20% life time though).  

Technical Data:

Product Name iso-Butylammonium Bromide 
Synonym
  • iBABr
  • i-BuNH3Br
  • iso-Butanamine hydrobromide
SKU#
CM7021
CAS Number 74098-36-5
Chemical Formula C4H12BrN
Molecular Weight  154.05
Appearance White Powder
Solubility Soluble in DMF, DMSO, EtOH et al.
Packaging 3 g, or as required in glass bottle
Store 25 ℃ under N2 atmosphere
Notes 1HNMR & user instruction for enquiring

References:

[1]: The Effect of Tert-butylammonium Addition in Methylammonium Lead Iodide Perovskite Solar Cells. In 2019 IEEE 46th Photovoltaic Specialists Conference (PVSC), pp. 1483-1486. IEEE, 2019.

[2]: Surface modification via self-assembling large cations for improved performance and modulated hysteresis of perovskite solar cells. Journal of Materials Chemistry A 7, no. 12 (2019): 6793-6800.

[3]: Effect of Steric Hindrance of Butylammonium Iodide as Interface Modification Materials on the Performance of Perovskite Solar Cells. Solar RRL (2022): 2200078.